learning theory
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This lecture begins a series describing the development of organic chemistry in chronological order, beginning with the father of modern chemistry, Lavoisier. The focus is to understand the logic of the development of modern theory, technique and nomenclature so as to use them more effectively. Chemistry begins before Lavoisier's "Chemical Revolution," with the practice of ancient technology and alchemy, and with discoveries like those of ...more
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This lecture explains what an economic model is, and why it allows for counterfactual reasoning and often yields paradoxical conclusions. Typically, equilibrium is defined as the solution to a system of simultaneous equations. The most important economic model is that of supply and demand in one market, which was understood to some extent by the ancient Greeks and even by Shakespeare. That model accurately fits the experiment from the last...more
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This lecture brings experiment to bear on the previous theoretical discussion of bonding by focusing on hybridization of the central atom in three XH3 molecules. Because independent electron pairs must not overlap, hybridization can be related to molecular structure by a simple equation. The "Umbrella Vibration" and the associated rehybridization of the central atom is used to illustrate how a competition between strong bonds and stable at...more
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Professor McBride uses this lecture to show that covalent bonding depends primarily on two factors: orbital overlap and energy-match. First he discusses how overlap depends on hybridization; then how bond strength depends on the number of shared electrons. In this way quantum mechanics shows that Coulomb's law answers Newton's query about what "makes the Particles of Bodies stick together by very strong Attractions." Energy mismatch betwee...more
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After pointing out several discrepancies between electron difference density results and Lewis bonding theory, the course proceeds to quantum mechanics in search of a fundamental understanding of chemical bonding. The wave function ψ, which beginning students find confusing, was equally confusing to the physicists who created quantum mechanics. The Schrödinger equation reckons kinetic energy through the shape of ψ. When ψ curves toward zer...more
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Why ethane has a rotational barrier is still debatable. Analyzing conformational and configurational stereotopicity relationships among constitutionally equivalent groups reveals a subtle discrimination in enzyme reactions. When Baeyer suggested strain-induced reactivity due to distorting bond angles away from those in an ideal tetrahedron, he assumed that the cyclohexane ring is flat. He was soon corrected by clever Sachse, but Sachse's w...more
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Youthful chemists Couper and Kekulé replaced radical and type theories with a new approach involving atomic valence and molecular structure, and based on the tetravalence and self-linking of carbon. Valence structures offered the first explanation for isomerism, and led to the invention of nomenclature, notation, and molecular models closely related to those in use today.
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Client Use of Templates, Vector Class, Vector Client Interface, Client Use of Vector, Type-safety in Templates, Grid Class, Grid Client Interface, Client Use of Grid, Stack Class, Stack Client Interface, Queue Class, Queue Client Interface, Client Use of Queue, Nested Templates, Learning a New API, CS106B Library Documentation
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In five years, New Schools has given 10,000 kids access to new schools, says Smith. Public charter schools provide an alternative to government-run schools by giving the school much more flexibility while maintaining accountability. She believes this flexibility encourages innovation and increased performance. Other portfolio items include: 1) Teachscape - an online teacher-training program, which uses a video case method of instruction ...more
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Lecture 8 of Leonard Susskind's Modern Physics concentrating on General Relativity. Recorded November 10, 2008 at Stanford University.
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Lecture 6 of Leonard Susskind's Modern Physics concentrating on General Relativity. Recorded October 27, 2008 at Stanford University.
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In 1989, following the year when Dell, Inc. went public, Dell explains how the company had a large problem with inventory management. As a result, the company failed to transition properly in the industry from one technology to the other. However, because of this critical mistake, the company learned how to correctly manage their inventory, and according to Dell, became the best in the world at it. Later on, Dell also notes the company did...more
