metals
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This course explores the basic principles of chemistry and their application to engineering systems. It deals with the relationship between electronic structure, chemical bonding, and atomic order. It also investigates the characterization of atomic arrangements in crystalline and amorphous solids: metals, ceramics, semiconductors, and polymers (including proteins). Topics covered include organic chemistry, solution chemistry, acid-base eq...more
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Review. Professor Sylvia Ceyer reviews the main topics covered throughout the second half of the course including kinetics, transition metals, VSEPR theory, acid-base equilibrium, chemical equilibrium, and oxidation/reduction. Professor Ceyer uses the case study of methionine synthase to supplement the discussion.
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Professor Sylvia Ceyer introduces the class to crystal field theory and ligand field theories. Several terms are defined, including octahedral field splitting energy, and the lecture concludes by using the octahedral crystal field splitting diagram with a few examples.
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Properties of alkali, alkaline earth and transition metals. Halogens and noble gases.
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Professor Sylvia Ceyer covers crystal field theory in both the tetrahedral case and the square planar case. The discussion then moves to the spectrochemical series and strong/weak field ligands. A conversation on magnetism, both paramagnetic and diamagnetic, in transition metals concludes the lecture.
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Professor Sylvia Ceyer introduces transition metals and the formation of coordination complexes. The Chelate effect is defined and the difference between geometric isomers and optical isomer (enantiomers) is discussed. The discussion concludes with d orbitals and d-electron counting in coordination complexes.
