organic chemistry,
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The movement of matter and energy around the planet is very important, and its study draws on geology, and meterology in addition to chemistry. Energy tends to flow upwards from plantlike producers to herbivores to carnivores before being decomposed by detritovores and cycling back into energy usable by producers, in addition to the photosynthesis or chemosynthesis used by producers to produce energy. Like energy, compounds vital to life s...more
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Oxidation and reduction in cellular respiration. Reconciling the biology and chemistry definitions of oxidation and reduction.
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Fundamental Growth - EPS versus Net Income - Organic vs Efficiency Growth -Operating Income Growth -Growth with money losing companies Terminal Value -Why multiples don't work - Consistency rules (Growth rate, Length of growth, Excess Returns)
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Thompson talks about how the cheapest form of growth is organic growth. We will be in the market again soon, he adds.
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Determination of the actual atomic arrangement in tartaric acid in 1949 motivated a change in stereochemical nomenclature from Fischer's 1891 genealogical convention (D, L) to the CIP scheme (R, S) based on conventional group priorities. Configurational isomers can be interconverted by racemization and epimerization. Pure enantiomers can be separated from racemic mixtures by resolution schemes based on selective crystallization of conglome...more
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Despite cautions from their conservative elders, young chemists like Paternó and van't Hoff began interpreting molecular graphs in terms of the arrangement of a molecule's atoms in 3-dimensional space. Benzene was one such case, but still more significant was the prediction, based on puzzling isomerism involving "optical activity," that molecules could be "chiral," that is, right- or left-handed. Louis Pasteur effected the first artificial...more
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This lecture begins by applying the united-atom "plum-pudding" view of molecular orbitals, introduced in the previous lecture, to more complex molecules. It then introduces the more utilitarian concept of localized pairwise bonding between atoms. Formulating an atom-pair molecular orbital as the sum of atomic orbitals creates an electron difference density through the cross product that enters upon squaring a sum. This "overlap" term is th...more
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