structure of federal law
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Professor Freeman discusses the debate over the Constitution at the Federal Convention of 1787 - a convention that by no means had an inevitable outcome. Indeed, even attending the Convention at all was a subject of debate in the individual states; many people feared that the Convention would produce a pseudo-monarchical form of government that would abandon the true significance of the Revolution. Ostensibly called to revise the Articles ...more
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In this lecture, Professor Freeman discusses how the new nation moved towards creating a stronger, more centralized national government than the Articles of Confederation. Complications of commerce between individual states - a factor that wasn't regulated by the Articles - led to a series of interstate gatherings, like the Mount Vernon Conference of March 1785. Some strong nationalists saw these meetings as an ideal opportunity to push to...more
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Although molecular mechanics is imperfect, it is useful for discussing molecular structure and energy in terms of standard covalent bonds. Analysis of the Cambridge Structural Database shows that predicting bond distances to within 1% required detailed categorization of bond types. Early attempts to predict heats of combustion in terms of composition proved adequate for physiology, but not for chemistry. Group- or bond-additivity schemes a...more
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Knowledge of historical context is crucial to understanding the New Testament. Alexander the Great, in his conquests, spread Greek culture throughout the Mediterranean world. This would shape the structure of city-states, which would share characteristically Greek institutions, such as the gymnasium and the boule. This would also give rise to religious syncretism, that is, the mixing of different religions. The rise of the Romans would con...more
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Half a century before direct experimental observation became possible, most structures of organic molecules were assigned by inspired guessing based on plausibility. But Wilhelm Körner developed a strictly logical system for proving the structure of benzene and its derivatives based on isomer counting and chemical transformation. His proof that the six hydrogen positions in benzene are equivalent is the outstanding example of this chemical...more
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In this lecture Professor Sylvia Ceyer covers the electron structure of multielectron atoms, beginning with simple electron configurations. The Aufbau Principle is explained, as well as the Pauli Exclusion Principle and Hund's Rule. Core electrons and valence electrons are discussed, concluding with electron configurations of ions and photoelectron spectroscopy.
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What does JetBlue think about organizational structure? We thought about how we would hire, train, set expectations and monitor to make sure this was actually happening, says Neeleman. We train employees well, and empower them and compensate them well, he adds.
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Youthful chemists Couper and Kekulé replaced radical and type theories with a new approach involving atomic valence and molecular structure, and based on the tetravalence and self-linking of carbon. Valence structures offered the first explanation for isomerism, and led to the invention of nomenclature, notation, and molecular models closely related to those in use today.
